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Mechanism for the amino-nitrile dissociation in the electrochemical reduction of hydrozone derivatives of nitrobenzaldehyde

✍ Scribed by Yu. M. Kargin; V. Z. Latypova; M. Yu. Kitaeva; A. A. Vafina; R. M. Zaripova; A. V. Il'yasov


Book ID
112445200
Publisher
Springer
Year
1984
Tongue
English
Weight
57 KB
Volume
33
Category
Article
ISSN
1573-9171

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At room temperature, the presence of hydrogen and catalytic amounts of Pd/C induced the formation of 1,3-oxazolidines from nitriles and 1,2-amino alcohols. The subsequent reductive cleavage of the NC-O bond of lhese heterocycles occurred under the same conditions. Thus, this methodology provides a n