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Mechanism for enantioselective hydrogenation of α-nitrocaprolactam on a chiral palladium catalyst

✍ Scribed by D. D. Gogoladze; E. S. Levitina; L. F. Godunova; E. I. Karpeiskaya; E. I. Klabunovskii; G. O. Chivadze

Book ID
112449164
Publisher
Springer
Year
1988
Tongue
English
Weight
359 KB
Volume
37
Category
Article
ISSN
1573-9171

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A highly enantioselective rhodium cataly
A highly enantioselective rhodium catalyst for the hydrogenation of aliphatic α-keto esters
✍ Dr. Felix Spindler; Ulrich Pittelkow; Hans-Ulrich Blaser 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 529 KB

The enantioselective hydrogenation of several a-keto acid derivatives with rhodium diphosphine catalysts has been investigated using a random screening approach. The neutral rhodium catalyst prepared in situ from bis(2,5norbornadiene rhodium chloride) and NORPHOS has been found to be an excellent ca