Mechanism and Stereochemistry of the Reaction of Dichloroplatinum(II) Complexes with Diazo Compounds. X-ray Structures of Four Key Products: [(2 R, 3 R )-Bis(diphenylphosphino)butane]chloro- [( S )-chloro(methoxycarbonyl)methyl]platinum(II), (η 4 -1,5-Cyclooctadiene)[3-chloro-5-(dimethoxyphosphonyl)-2- methoxy-4,1,2-platinaoxaphospholane P -oxide], ( R,R) -[Chloro(dimethoxyphosphonyl)methyl][chloro- (trimethylsilyl)methyl](1,5-cyclooctadiene)platinum(II), and Chloro[chloro(dimethoxyphosphonyl)methyl](η 4 -1,5-cyclooctadiene)platinum(II)

✍ Scribed by Ferguson, George; Gallagher, John F.; McAlees, Alan J.; McCrindle, Robert

• Book ID: 127116537
• Publisher: American Chemical Society
• Year: 1997
• Tongue: English
• Weight: 191 KB
• Volume: 16
• Category: Article
• ISSN: 0276-7333
• DOI: 10.1021/om9607964