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Mechanism and kinetics of thermolysis of ethers modelling the oxygen-methylene ‘bridge’ bonds in coal organic matter

✍ Scribed by V.Yu. Korobkov; E.N. Grigorieva; V.I. Bykov; I.V. Kalechitz


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
830 KB
Volume
16
Category
Article
ISSN
0165-2370

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Effect of the structure of coal-related
✍ Vjacheslav Yu. Korobkov; Evgenija N. Grigorieva; Victor I. Bykov; Oleg V. Senko; 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 627 KB

The constants of thermolysis rate of C,H,~(CH,),~O~(CH,),-C6HS ethers were measured in conditions close to those of coal liquefaction (hydrogen pressure of 8.5 MPa; temperature up to 410°C) but minimizing secondary conversions (i.e. in ten-fold excess of tetralin). The ethers form the following reac