Kinetics and thermochemistry of the reac
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Sidney W. Benson
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Article
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1994
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John Wiley and Sons
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English
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The shock tube data of Ogura [51 on the pyrolysis of CzHz/NO mixtures (1100-1500 K) is shown to be consistent with a simple mechanism whereby radicals are both initiated and terminated by NO (Scheme I). The scheme accounts for the rate of formation of the main product, vinylacetylene (VA), the lesse