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Mechanism and Kinetics of the Catalytic CO−H 2 Reaction: An Approach by Chemical Transients and Surface Relaxation Spectroscopy †

✍ Scribed by Frennet, Alfred; Visart de Bocarmé,, Thierry; Bastin, Jean-Marie; Kruse, Norbert


Book ID
126911866
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
630 KB
Volume
109
Category
Article
ISSN
0022-3654

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## Abstract The kinetics of the H~2~O~2~ decomposition by Cu(II)‐, Co(II)‐, and Fe(III)‐amine complexes supported on the surface of silica‐alumina (25% Al~2~O~3~) catalyst have been investigated. The decomposition process proceeded with first‐order kinetics for the substrate concentration. With cop