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Mechanism and kinetics of radiolytically initiated cyclohexyl radical addition to cis- and trans-1,2-dichloroethylene and of the subsequent chlorine atom elimination reaction

โœ Scribed by Horowitz, Abraham.; Rajbenbach, L. A.


Book ID
126288625
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
482 KB
Volume
92
Category
Article
ISSN
0002-7863

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โœ A. Horowitz; G. Baruch ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 899 KB

The addition reactions of CC13 radicals with cis-CzClzHz, trans-CzClzHz, and CzC13H in liquid cyclohexane-CC14 mixtures were studied between 323 and 448 K. The Arrhenius parameters of these reactions were competitively determined versus H-atom transfer from cyclohexane and addition to C2C14. The pre