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Mechanism and kinetics of fluorescence quenching of aromatic hydrocarbons by a stable nitroxyl radical

โœ Scribed by Jerzy Karpiuk; Zbigniew R. Grabowski


Book ID
107734628
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
463 KB
Volume
160
Category
Article
ISSN
0009-2614

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Formation of triplets of aromatic hydroc
โœ V.A. Kuzmin; A.S. Tatikolov ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 237 KB

Quenching of aromatic excited singlet states (9,10-dimethyl anthracene, 9,10-diphenyl anthracene and perylene) by nitroxyl radical was studied by flash photolysis and fluorimetrically. It is established that the dominant quenching mechanism is enhanced intersystem crossing in the collision complex w