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Mechanism and kinetics of carbothermal metal oxide reduction in graphite atomic-absorption ovens

โœ Scribed by B. V. L'vov; A. S. Savin; L. F. Yatsenko

Publisher
Springer US
Year
1985
Tongue
English
Weight
433 KB
Volume
43
Category
Article
ISSN
0021-9037

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The electron transfer step of the reduction of Mn(acac)s and Co(acac)s by Fe(I1) in acetonitrile is preceded by the one-ended dissociation of an acac ligand and the formation of a binuclear bridged complex. After the electron transfer has taken place through the bridging ligand, the complex dissocia