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Mechanism and Dynamics of Azobenzene Photoisomerization

✍ Scribed by Schultz, Thomas; Quenneville, Jason; Levine, Benjamin; Toniolo, Alessandro; Martínez, Todd J.; Lochbrunner, Stefan; Schmitt, Michael; Shaffer, James P.; Zgierski, Marek Z.; Stolow, Albert


Book ID
111943101
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
86 KB
Volume
125
Category
Article
ISSN
0002-7863

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Photoisomerization of sterically hindere
✍ Hermann Rau; Shen Yu-Quan 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 512 KB

The photoisomerization yields of a homologous series of o,o,o',o'substituted azobenzenes have been determined by excitation of the low lying l(n,~\*) and the higher lying I(~F,~F\*) states. For more severe steric hindrance, i.e. with substituents more bulky than methyl, the E + 2 quantum yields are