Mechanical properties of multilayered chitosan/CNT nanocomposite films

✍ Scribed by Fangfang Sun; Hee-Ryoung Cha; KiEun Bae; Suckwon Hong; Jong-Man Kim; Soo Hyung Kim; Jaebeom Lee; Dongyun Lee

• Publisher: Elsevier Science
• Year: 2011
• Tongue: English
• Weight: 964 KB
• Volume: 528
• Category: Article
• ISSN: 0921-5093
• DOI: 10.1016/j.msea.2011.05.028

✦ Synopsis

A multi-performance MWCNT-reinforced chitosan nanocomposite was fabricated by two methods: a freeze-drying process associated with the sublimation and compression (SAC) method; and the castingevaporation (CE) method. We obtained ordered and multilayered structures with limited porosity, and well-dispersed MWCNT structures of the chitosan nanocomposite, especially with the SAC method. In the case of the nanocomposite films prepared by the CE method, the mechanical strength and elongation were significantly increased by up to about 40% compared with the pure chitosan films. On the other hand, the ordered and porous multilayered pure chitosan films prepared by the SAC method showed significantly lower tensile strength and elongation compared to the pure solid chitosan films. However, the relative enhancement of the mechanical properties of multilayered MWCNT/chitosan nanocomposites with porosity was higher, especially in terms of the elongation, which showed a twofold improvement in strain. The relaxed bond, which could be a relatively strong hydrogen bond, between the functional groups in the chitosan chains and the functionalized surface of the MWCNTs might be stretched under stress, thereby improving the ductility of the multilayered nanocomposite films. In addition, the viscoplastic behavior of the films by the CE method could become more active with increasing strain rate. Interestingly, ordered and porous pure chitosan films did not reveal the viscoplastic behavior; it rather presented strain softening and viscoelastic characteristics. However, the interaction between the chitosan chains and the surface-modified MWCNTs could regenerate viscoplasticity of the chitosan films.