Glass transition temperatures of poly(ethyl acrylate-vinylidene chloride) and reactivit.~ ratios for the copolymerization of the parent monomers are reported. All the copolymers have glass transition temperatures higher than those of polyethylacrylate or polyvinylidene chloride: the copolymer contai
Mechanical properties and transition temperatures of copolymers of N-n-alkylacrylamides and vinylidene chloride
β Scribed by Edmund F. Jordan; George R. Riser Jr.; Bohdan Artymyshyn; Winfred E. Parker; John W. Pensabene; A. N. Wrigley
- Publisher
- John Wiley and Sons
- Year
- 1969
- Tongue
- English
- Weight
- 795 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0021-8995
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A series of vinylidene chloride (VDC) copolymers with methyl acrylate (MA) or butyl acrylate (BA) as comonomer (not more than 10%) was prepared by free-radical suspension copolymerization. The effects of comonomer structure, copolymer composition, and reaction condition (such as polymerization tempe
The minimum temperature required for a copolymer emulsion to form a continuous film, T,r, and the glass transition temperature T, of the copolymer were studied for vinylidene chloride-acrylate copolymers and vinylidene chloride-acrylonitrile copolymers. The T,r and T, were studied as a function of