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Mechanical and thermo-mechanical studies of double networks based on thermoplastic elastomers

✍ Scribed by Naveen K. Singh; Alan J. Lesser


Book ID
105339346
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
981 KB
Volume
48
Category
Article
ISSN
0887-6266

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✦ Synopsis


Abstract

A new approach to prepare and characterize double network elastomeric systems was investigated. A styrene‐ethylene‐co‐butylene‐styrene (SEBS) triblock copolymer system containing physical crosslinks was used to achieve a double network by additional crosslinking using ultra‐violet (UV) light. An ethylene–propylene–diene monomer (EPDM) terpolymer system containing chemical crosslinks was used to achieve a conventional double network using UV crosslinking. Properties from conventional monotonic tensile tests, dynamic mechanical analysis, and thermomechanical properties were investigated. These double network elastomers show a transition between competitive and collaborative behavior in their mechanical properties and lower coefficients of thermal expansion arising from a competition of the networks. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 778–789, 2010


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