Mechanical and thermo-mechanical studies of double networks based on thermoplastic elastomers
✍ Scribed by Naveen K. Singh; Alan J. Lesser
- Book ID
- 105339346
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 981 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0887-6266
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✦ Synopsis
Abstract
A new approach to prepare and characterize double network elastomeric systems was investigated. A styrene‐ethylene‐co‐butylene‐styrene (SEBS) triblock copolymer system containing physical crosslinks was used to achieve a double network by additional crosslinking using ultra‐violet (UV) light. An ethylene–propylene–diene monomer (EPDM) terpolymer system containing chemical crosslinks was used to achieve a conventional double network using UV crosslinking. Properties from conventional monotonic tensile tests, dynamic mechanical analysis, and thermomechanical properties were investigated. These double network elastomers show a transition between competitive and collaborative behavior in their mechanical properties and lower coefficients of thermal expansion arising from a competition of the networks. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 778–789, 2010
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