Measurements and Calculations of the Halfwidth of Two Rotational Transitions of Water Vapor Perturbed by N2, O2, and Air
โ Scribed by Jean-Marcel Colmont; Dominique Priem; Georges Wlodarczak; Robert R. Gamache
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 163 KB
- Volume
- 193
- Category
- Article
- ISSN
- 0022-2852
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โฆ Synopsis
In this paper we report the results of both an experimental and theoretical study of the halfwidths of two transitions of water vapor. Measurements on the lines of the H 2 16 O and H 2 18 O isotopomers located at 325.1 and 203.4 GHz, respectively, were carried out in the temperature range 300 -393 K, with N 2 and O 2 as perturbing gases. The foreign-broadening coefficients and their temperature-dependence parameters were determined assuming a Voigt profile and the usual temperature dependence for the halfwidth. The retrieved values are compared to values calculated using the complex semiclassical formalism of Robert and Bonamy. The assumed intermolecular potential is a combination of electrostatic and atom-atom components. This last contribution is defined as the sum of pairwise Lennard-Jones 6 -12 interactions between the atoms of H 2 O and the atoms of the perturbing molecules expanded to eighth order. Also calculated are the pressure-induced shifts of the spectral lines for temperatures from 200 to 400 K. Calculated and experimental results are in good agreement, within ฯฎ3.2%, except for the N 2 -broadening temperature coefficients, for which there are discrepancies as high as 23%. Air-broadening parameters are determined following the classical relation: โฅ (air) ฯญ 0.79โฅ (N 2 ) ฯฉ 0.21โฅ (O 2 ).
๐ SIMILAR VOLUMES
Absorption linewidths associated with microwave transitions across -doublets and pure rotational transitions of the free hydroxyl radical OH perturbed by N 2 , O 2 , and Ar are computed for temperatures ranging from 194 to 300 K within the framework of the Robert-Bonamy semiclassical formalism using
The pressure-induced shifting coefficients for self-, He-, Kr-, O 2 -, and N 2 -broadened lines of CO in the first overtone band have been measured using a tunable difference-frequency laser spectrometer. The lineshift was directly obtained from the simultaneous record of the pressure-broadened line