Using a Fourier transform spectrometer, we have recorded the spectra of ozone in the region of 4600 cm 01 , with a resolution of 0.008 cm 01 . The strongest absorption in this region is due to the n 1 / n 2 / 3n 3 band which is in Coriolis interaction with the n 2 / 4n 3 band. We have been able to a
Measurements and Calculations of Room-Temperature Ozone Line-Broadening by N2 and O2 in the ν1 +ν 3 Band
✍ Scribed by S. Bouazza; A. Barbe; J.J. Plateaux; L. Rosenmann; J.M. Hartmann; C. Camypeyret; J.M. Flaud; R.R. Gamache
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 679 KB
- Volume
- 157
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
A high-resolution Fourier transform spectrometer has been used to record a large number of spectra, with ozone and foreign gas pressures ranging from 5 to 50 Torr and 80 to 700 Torr, respectively. The (2100-\mathrm{cm}^{-1}) region corresponding to the (\nu_{1}+\nu_{3}) band of (\mathrm{O}{3}) has been analyzed and the broadening coefficients by (\mathrm{N}{2}) and (\mathrm{O}{2}) at room temperature have been derived for 112 lines with an accuracy better than (3 \times 10^{-3} \mathrm{~cm}^{-1} \mathrm{~atm}^{-1}). This study covers a wide range of rotational quantum numbers (\left(J^{\prime \prime}=0-40, K{a}^{\prime \prime}=0-11\right)) in an (A)-type band (\left(\nu_{1}+\nu_{3}\right)). Calculations of these broadening coefficients have been performed with a theoretical model successfully tested on (\mathrm{H}{2} \mathrm{O}) linewidths. This model provides a correct modeling of close collisions since the contributions of an atom-atom potential and trajectory modifications at short distance are accounted for. It has been previously applied to (\mathrm{O}{3}) line broadening by (\mathrm{N}{2}) and (\mathrm{O}{2}) but only a dozen of (B) type lines were then investigated. In the present study, the atom-atom parameters for the (\mathrm{O}{3}-\mathrm{N}{2}) and (\mathrm{O}{3}-\mathrm{O}{2}) interactions have been adjusted to match experiment since no intermolecular anisotropic potential is, to our knowledge, available for (\mathrm{O}{3}). The standard deviations between experimental and theoretical results are about (6 %), with absolute maximum deviations of about (14 %) for (\mathrm{O}{3}-) (\mathrm{N}{2}) and (\mathrm{O}{3}-\mathrm{O}{2}). Furthermore, use of simple empirical polynomial corrections of calculated results versus rotational quantum numbers leads to agreement between observations and calculations better than (2 %) for the (\mathrm{O}{2}) and (\mathrm{N}_{2}) broadenings of most lines. 氏í 1993 Academic Press. Inc.
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