The anisotropy of the chemical shift tensor in solid fluorine has been measured by several independent methods to he (1050\*50} x 10-6. This value is slightl,v smaller than the estimated paramagcetic part of the chemical shift from the spin-rotation constant in the gaseous state.
โฆ LIBER โฆ
Measurement of some chemical shifts in a solid fluorine polymer
โ Scribed by Ellett, D. ;Haeberlen, U. ;Waugh, J. S.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1969
- Tongue
- English
- Weight
- 159 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0449-2986
No coin nor oath required. For personal study only.
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## Abstract At the present time no completely satisfactory quantum mechanical calculations exist for carbon, proton or fluorine chemical shifts in various substituted aromatic or olefinic systems. However, the chemical shifts in such systems have been shown to be well correlated by a linear multipl