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Measurement of some chemical shifts in a solid fluorine polymer

โœ Scribed by Ellett, D. ;Haeberlen, U. ;Waugh, J. S.


Publisher
Wiley (John Wiley & Sons)
Year
1969
Tongue
English
Weight
159 KB
Volume
7
Category
Article
ISSN
0449-2986

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๐Ÿ“œ SIMILAR VOLUMES


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The anisotropy of the chemical shift tensor in solid fluorine has been measured by several independent methods to he (1050\*50} x 10-6. This value is slightl,v smaller than the estimated paramagcetic part of the chemical shift from the spin-rotation constant in the gaseous state.

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## Abstract At the present time no completely satisfactory quantum mechanical calculations exist for carbon, proton or fluorine chemical shifts in various substituted aromatic or olefinic systems. However, the chemical shifts in such systems have been shown to be well correlated by a linear multipl