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Measurement and analysis of the Fermi resonance between ν5 and 2ν9 of nitric acid

✍ Scribed by A.G. Maki; J.S. Wells


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
815 KB
Volume
152
Category
Article
ISSN
0022-2852

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Using Fourier transform spectra recorded at 25 and \(12 \mu \mathrm{m}\), it has been possible to perform the first analysis of the \(3 \nu_{9}-2 \nu_{9}, 3 \nu_{9}-\nu_{5}\) and \(3 \nu_{9}-\nu_{9}\) hot bands of \(\mathrm{HNO}_{3}\) located at \(392.4 \mathrm{~cm}^{-1}\), \(409.8 \mathrm{~cm}^{-1}

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The high-resolution FTIR spectrum of the n 8 / n 9 band of HNO 3 around 1205 cm 01 has been measured and analyzed. The bright state was found to be strongly perturbed by its neighboring dark state n 6 / n 7 at the coincident levels. Taking account of the DK Å {2 anharmonic resonance, a simultaneous