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Me3SiCl-assisted 1,2-addition of organocuprates to carbonyl compounds

✍ Scribed by Satoshi Matsuzawa; Masahiko Isaka; Eiichi Nakamura; Isao Kuwajima


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
232 KB
Volume
30
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Diastereoselective organocuprate additio
✍ Michael E. Jung; Willard Lew πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 251 KB

Addition of lower or higher order cuprates to the enone homoketals 4a-d give the alkylated products with de's ranging from 12% to 34%. The efftcient production of optically active materials from prochiral precursors by asymmetric induction is one of the goals in synthetic organic chemistry today.1