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MCSCF-Cl calculations of the CO+ ion

✍ Scribed by H. Lavendy; J.M. Robbe; J.P. Flament

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
377 KB
Volume
205
Category
Article
ISSN
0009-2614

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✦ Synopsis

Multicontiition self-consistent tield+configuration interaction wavefunctions were used to compute potential energy curves of the lowest doublet and quadruplet states of CO*. Spin-orbit splitting the three lowest 'II states and dipole moment for the X *Z+, A 'IL and D 'lT states bave been determined. Transition moments for the A 'D-X 'Z+, D 'II-X 'Z+, ( 3)*lI-X 'Ef, D *II-A 'IT and B *2+-A *II transitions have been calculated. Theoretical oscillator strengths for the D 'D-X 2X+ and D ZlT-A21T transitions were calculated and the results show that these transitions could be observed.

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