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Matrix Preparation and Spectroscopic and Theoretical Investigations of Simple Methylidene and Methylidyne Complexes of Group 4—6 Transition Metals

✍ Scribed by Lester Andrews; Han-Gook Cho

Publisher: John Wiley and Sons
Year: 2006
Weight: 8 KB
Volume: 37
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200648231

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## Abstract It is shown that ligand **1**, designed to span __trans__‐positions, under appropriate conditions also gives __cis__‐mononuclear complexes of platinum (II). The structure of __cis__‐[PtCl~2~ **(1)**] **(2)** has been determined by single‐crystal X‐ray diffraction. The major distortion f