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Matrix Photochemistry

โœ Scribed by Ian R. Dunkin

Book ID
101955819
Publisher
John Wiley and Sons
Year
2004
Weight
47 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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Tetrafluoro-p-xylylene (3) has been generated by flash by comparison of experimental and calculated IR spectra. The temperature-dependence of the thermal fragmentation vacuum pyrolysis of octafluoro[2.2]paracyclophane (2) and subsequent trapping of the products in solid argon at 9 K. of paracyclop

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## Abstract The UV photolysis of [2.2]paracyclophanโ€ene (3) and benzoโ€[2.2]paracyclophanโ€ene (4), matrixโ€isolated in argon at 10 K, results in the cleavage of the ethano bridge and formation of compounds 5 and 8, respectively. The IR and UV/Vis spectra are compared with __p__โ€xylylene and the benzy