Water and ethylene form a weak molecular complex in argon matrIces\_ Water is hydrogen-bonded to the m-orbital of ethylene. For the HDO complex, only D-bonding is observed A romplex containing two water molecules and one ethylene has been observed This complex can be described ax a water dimer where
Matrix isolation studies of the interaction of cyclopropane with strong lewis acids
β Scribed by Candace E. Truscott; Bruce S. Ault
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 347 KB
- Volume
- 157
- Category
- Article
- ISSN
- 0022-2860
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## Infrared spccrra of qctopropane-hydrogen halide and cyclopropane-water complexes show similar perturbations of the cyclopropane modes, su:zestins that al: have the proton donor "hydrogen-bonded" to the ring ease\_ The spectrum of the cyclopropane-water comple\ is consistent with water forming a
Interaction of metal complexes of linearly benzo-annulated tetraazaporphyrins such as tetra-tert-butyltetrabenzoporphyrazine, tetra-tert-butyltetranaphthoporphyrazine, and octaphenyltetraanthraporphyrazine, with the Lewis acid AlBr 3 in nitrobenzene and ethylbromide has been studied by absorption sp