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Matrix isolation IR and Raman studies of the molecules Na2SO4 and K2SO4

✍ Scribed by R.M. Atkins; K.A. Gingerich

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 292 KB
Volume: 53
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)85413-x

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✦ Synopsis

IR and Raman spectra have been obtained of NazSOa and KzSO4 molecules, present over the heated crystalline sulphates, in argon and nitrogen matrices at 12 K. t+d symmetry is indicated for these molecules. Evidence of agregation on warming *the matrix has been observed. Sublimation of Na2S04 was accompanied by partial decomposition. No decomposition WaS detected for K2SO4.

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