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Matrix-Isolation Infrared Spectroscopy of the Rotational Isomers of 1,2-, 1,3-, and 1,4-Benzenedicarboxaldehyde

✍ Scribed by Ohno, Keiichi; Itoh, Takao

Book ID: 126216651
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 119 KB
Volume: 111
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp071330+

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## Abstract 1‐Alkylcyclohepta[__b__]pyrrol‐2(1__H__)‐ones showed rotational isomerism around the CN bond. Two rotamers of the 1‐(2,4‐dimethyl‐3‐pentyl) derivative were isolable by high‐performance liquid chromatography at 0°C. The activation free energy, measured by the line‐shape analysis of the