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Matrix-Isolation Infrared Spectroscopy of Organic Phosphates

โœ Scribed by George, Lisa; Sankaran, K.; Viswanathan, K. S.; Mathews, C. K.

Book ID
115362313
Publisher
Society for Applied Spectroscopy
Year
1994
Tongue
English
Weight
523 KB
Volume
48
Category
Article
ISSN
0003-7028

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๐Ÿ“œ SIMILAR VOLUMES

Matrix isolation-supersonic jet infrared
Matrix isolation-supersonic jet infrared spectroscopy: conformational cooling in trimethyl phosphate
โœ V. Vidya; K. Sankaran; K.S. Viswanathan ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 371 KB

A supersonic jet source has been coupled to a matrix isolation set-up to obtain conformational cooling in organic phosphates. Infrared spectra of trimethyl phosphate (TMP) trapped in a nitrogen matrix using supersonic jet sampling, indicated that the higher-energy conformer of TMP was significantly