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Matrix-isolation infrared and ultraviolet?visible studies on some transition-metal pentachlorides and pentabromides

✍ Scribed by Bellingham, Richard K.; Graham, John T.; Jones, Peter J.; Kirby, Julia R.; Levason, William; Ogden, J. Steven; Brisdon, Alan K.; Hope, Eric G.


Book ID
121085288
Publisher
The Royal Society of Chemistry
Year
1991
Tongue
English
Weight
815 KB
Volume
12
Category
Article
ISSN
1472-7773

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one complexes of ammonia with the neutral transition metals, Cu and Fe, have been formed in solid argon matrices at 12 K and investigated spectroscopically in the infrared region. FTIR spectra reveal large shifts in the us NHs umbrella mode upon complexation with these transition metal atoms. The pr