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Matrix isolation and theoretical study of the photochemical reaction of CH3CN with CrO2Cl2 and OVCl3

✍ Scribed by Nicola Goldberg; Sarah R. Lubell; Bruce S. Ault

Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
338 KB
Volume
740
Category
Article
ISSN
0022-2860

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## Abstract A dual‐level direct dynamic method is employed to study the reaction mechanisms of CF~3~CH~2~OCHF~2~ (HFE‐245fa2; HFE‐245mf) with the OH radicals and Cl atoms. Two hydrogen abstraction channels and two displacement processes are found for each reaction. For further study, the reaction m

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The matrix isolation technique, combined with infrared spectroscopy, has been used to characterize the products of the photochemical reactions of cyclohexane and cyclohexene with CrCl 2 O 2 . While initial twin jet deposition of the reagents led to no visible changes in the recorded spectra, strong