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Matrix Infrared Spectra and ab Initio Calculations of the Formohydroxamic Acid Complexes with HF and HCl

✍ Scribed by Sałdyka, Magdalena; Mielke, Zofia


Book ID
126146526
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
125 KB
Volume
107
Category
Article
ISSN
1089-5639

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Infrared matrix isolation studies of the
✍ Magdalena Sałdyka; Zofia Mielke 📂 Article 📅 2004 🏛 Elsevier Science 🌐 English ⚖ 149 KB

Argon matrix infrared spectra of the complexes formed between acetohydroxamic acid (CH 3 CONHOH) and hydrogen halides (HF, HCl) have been recorded. The experimental results indicate formation of a strong binary complex in which the hydrogen halide molecule acts as a proton donor towards the carbonyl