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Matrix Effects on Spin−Lattice Relaxation in the Triplet State of Tryptophan

✍ Scribed by Wu, Jie Q.; Ozarowski, Andrzej; Maki, August H.

Book ID
127316284
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
172 KB
Volume
101
Category
Article
ISSN
1089-5639

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✍ B. F. Minaev; Yu. A. Serebrennikov 📂 Article 📅 1978 🏛 Springer 🌐 English ⚖ 298 KB

A new mechanism is proposed for spin-lattice relaxation (SPL) in the phosphorescent triplet state of a molecule that has no inversion point. The mechanism is based on the fact that the internal spin-orbital interaction in a molecule allows the transition between spin sublevels of the triplet induced