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Matrix effect on the photochemistry of cyclopropyl ketones. Photochemistry of the triplet state of 2-spirocyclopropyl-1-indanone at 77 K

✍ Scribed by Loutfy, Rafik O.; Yates, Peter


Book ID
126797474
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
590 KB
Volume
101
Category
Article
ISSN
0002-7863

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Effect of rotational quantum states (J=0
✍ Fujitani Yoshiteru; Miyazaki Tetsuo; Masaki Nobuyuki M.; Aratono Yasuyuki; Tachi πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 348 KB

The effect of rotational quantum states (J=O, 1) on the tunneling reaction H2 t T+ H t HT in solid Xe-HI-D2 mixtures has been studied at 77 K. When T atoms are produced by a 6Li(n, a)T reaction in xenon-hydrogen (1 mol%) mixtures, most recoil T atoms are thermalized before encountering the solute hy