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Matrix dependence of the conformations of the 1,4-diethylbenzene radical cation at low temperatures

✍ Scribed by Y. Kubozono; M. Okada; T. Miyamoto; M. Ata; Y. Gondo; M. Shiotani; S. Yasutake

Book ID
103907702
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
415 KB
Volume
48
Category
Article
ISSN
1386-1425

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✦ Synopsis

Ahatraet-1,4-Diethylbenxene radical cation generated in six different halocarbon matrices by "Co y-ray irradiation has been studied by ESR at low temperatures. The spectra exhibit drastic variations in diierent matrices, showing that the conformation of the radical cation is largely dependent on the matrix.

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The temperature dependences of hydroxyl group proton and ring proton isotropic hyperÐne coupling constants (IHFC) of 1,4-hydroquinone (HQ) and 1,4-dihydroxynaphthalene (NQ) cation radicals were measured by electron paramagnetic resonance spectroscopy. The spectral parameters were obtained in the tem