Matrix and ab initio infrared spectra of germanium carbonyls
β Scribed by Antonio Feltrin; Stella Nunziante Cesaro; Fabio Ramondo
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 558 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0924-2031
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π SIMILAR VOLUMES
The equilibrium geometry of linear CXO has been calculated with high precision ( ~0.0005 8, accuracy) by combining experimental ground-state rotational constants and theoretical vibration-rotation coupling constants. The results are R,,( C,-C,) = 1.27 I7 A, R2e(C2-C3) = 1.2965 A and R,,(C3-0) = 1.14
Conformations of dimethoxymethylphenylsilane (DMMPS) were studied using matrix isolation infrared spectroscopy and ab initio computations. DMMPS was trapped in both argon and nitrogen matrixes, using an effusive nozzle source and a supersonic jet source. In order to corroborate our experimental obse