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Mathematical model of interdiffusion in multi-component open systems showing concentration dependent intrinsic diffusivities

✍ Scribed by Robert Filipek


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
409 KB
Volume
86
Category
Article
ISSN
0167-7322

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✦ Synopsis


The generalized Darken model ofinterdiffusion is presented. This model is valid for an open and closed system and when intrinsic diffusivities vary with composition. The method of calculation of the intrinsic diffusivities is presented.

The practical applications of the model are presented. The intrinsic diffusion coefficients in ternary Cr-Fe-Ni system are determined. Then the evolution of the Cr-Ni steels because of its oxidation is presented, i.e., the interdiffusion in open system due to reaction at the boundary. The computer simulation ofinterdiffusion process in binary Au-Ni alloy system in which diffusivities markedly vary with composition is shown.