## Phenylchlorocarbenes , produced by photolysis of the parent diazirines, have a very limited lifetime in alkane solvents. The rate of dibappearance of p-methyl-and p-chlorophenylchlorocarbenes has been measured in iso-octane, cyclohexane and n-hexane as well as in benzene for comparison. The rat
Mathematical model for the measurement of pseudo-first-order rate constants in laser flash photolysis experiments
β Scribed by John F. Cassidy; Conor Long
- Book ID
- 108043306
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 693 KB
- Volume
- 54
- Category
- Article
- ISSN
- 1010-6030
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π SIMILAR VOLUMES
Absolute rate constants for the addition of the highly nucleophilic 2-hydroxy-2-propyl radical to eight fast-reacting 1and 1,l-disubstituted alkenes in MeOH at room temperature have been determined by laser flash photolysis. Also the absorption spectra of the 2-hydroxy-2-propyl and the benzylic and
Five low rank, coal-based adsorbents, i.e. coal, grus, two chars, and an activated carbon were used to adsorb a low molecular weight organic compound from aqueous solution. The rates of adsorption were found to conform to pseudo ΓΌrst order kinetics with good correlation (r2 greater than 0.996). This