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Mass transfer with chemical reaction

✍ Scribed by J.G. van de Vusse


Publisher
Elsevier Science
Year
1961
Tongue
English
Weight
720 KB
Volume
16
Category
Article
ISSN
0009-2509

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✦ Synopsis


A descnptlon IS given of the kmetlcs of simultaneous mass transfer and chemical reactions as occurrmg m gas-hqmd systems Expressions have been derived for the over-all reaction rate both for the stationary and the unsteady state Use has been made of the film theory and of the penetration theory The case of a reactlon of zero order in the gaseous compound, which has not yet been dealt with m hterature, 1s treated -This case IS often encountered m oxldatlon reactions of hydrocarbons It 1s shown that at high transfer rates the over-all reactlon rate ~111 approach the chenucal reactlon rate R&aum&L'auteur doMe une descnptlon de la cm&que du transfert de mat&e et des r4actlons chlmlques se pr&entant sunultan6ment dans des syst6mes gaz-hqmde 11 a dbdmt des Bquatlons pour la vltesse r&actlonnelle totale aussl blen pour l'&at stationmure que pour 1'6tat non-statlonnalre, en se servant des th6ones de la couche mmce et de la p&&ratlon Le cas d'une &action d'ordre z&o par rapport au wmpod gazeux, qm n'a pas encore 6ti mentlonnb dans la htt&ature, est trcut.6 Ce cas se prdaente souvent dans lea r&ctlons d'oxydatlon d'hydrocarbures L'auteur dt5montre qu'8 de hautes vltesses de transfert, la vltesse r&ctlonnelle totale s'approchera de la vltesse rbactionnelle chmuque Zusammenfassung-In manchen Gas-Flusslg-Systemen finden Massenubergang und chemlsche Reaktlonen gleichzeltlg statt Die Kmetlk &eser gleichzelttlg vor such gehenden Prozesse wud bescbrleben Fur tie gesamte Reaktlonsgeschwmtigkeit, sowohl un statlonaren als 1111 mchtstatlonaren Zustand, wurden mlt Htie der Fh-und der Durchdrmgungstheone Formelausdrucke abgeleltet Femer wlrd der Fall emer Reaktlon nullter Ordung (bezogen auf tie gasformlge Komponente) behandelt, der bls Jetzt m der Llteratur unberuckslcht@ gebheben 1st Em solcher Fall tntt haufig m Oxydatlonsreaktlonen von Kohlenwasserstoffen em Es \nrd gezelgt, dass Hch be1 hohen Ubergangsgeschwm&gkelten die gesamte Reaktlonsgeschwmdlgkelt der chemLschen Reaktlonsgeschwmdkelt annahert 1


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