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Mass transfer and kinetics study on the sulfite forced oxidation with manganese ion catalyst

✍ Scribed by Zhao Bo; Li Yan; Zhuo Yuqun; Tong Huiling; Zhang Xiaowen; Chen Changhe

Book ID
107513758
Publisher
Springer US
Year
2007
Tongue
English
Weight
546 KB
Volume
24
Category
Article
ISSN
0256-1115

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Kinetic and Mechanistic Studies on the O
Kinetic and Mechanistic Studies on the Oxidation of Nitrogen(III) (HNO2/) by the Tris(biguanide)manganese(IV) Ion in Aqueous Acidic Media
✍ Amit Das; Subrata Mukhopadhyay πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 124 KB πŸ‘ 2 views

## Abstract The kinetics of a net two‐electron transfer between an authentic Mn^IV^ complex, [Mn(bigH)~3~]^4+^ (__Fig.β€…1__; bigH = biguanide = C~2~N~5~H~7~), and nitrite in aqueous solution in the pH interval 2.00–3.60 is described. Stoichiometric data for the reaction clearly indicates Ξ”[Mn^IV^]/Ξ”