Mass spectroscopy of indolo[2,3-a]quinolizidines. I. Fragmentation patterns of C-3, C-4, C-6, C-7, and C-12b deuterated derivatives
β Scribed by Gribble, Gordon W.; Nelson, Randall B.
- Book ID
- 126176537
- Publisher
- American Chemical Society
- Year
- 1974
- Tongue
- English
- Weight
- 699 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0022-3263
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## Stereochemical control ' the preparation of 2substituted 1,2,3,4,6,7,12,12b-octahy~~oindoloI2,3-a,quinolizines possessing at will the C(12b)H-C(2)H cis or configuration trans was achieved by catalytic reduction ofthe 2,3-dehydro analoques, which were either unsubstituted on the indole nitrogen
Regioselective deuteration of 1-X-C 2 B 10 H 12 (X β«Χ‘β¬ 2, 7) cage systems with C 6 D 6 /AlCl 3 is correlated to ab initio calculational results on a [C 2 B 10 H 13 ] β«Χβ¬ intermediate. Full geometry optimizations of pertinent [C 2 B 10 H 13 ] β«Χβ¬ isomers, derived from each of the two 1-X-C 2 B 10 H 1