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Mass Spectrometry of the Organic Hydrate 2-Bromo-3,3-dihydroxy-1-(2-thienyl)-4,4,4-trifluoro-1-butanone

✍ Scribed by Bogdan Kralj; Dušan Žigon; Janez Košmrlj; Slovenko Polanc

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
297 KB
Volume
11
Category
Article
ISSN
0951-4198

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✦ Synopsis

The ionized molecular species obtained by electron impact and chemical ionization of the organic hydrate 2-bromo-3,3-dihydroxy-(2-thienyl)-4,4,4-trifluoro-1-butanone were analysed using the mass-analysed ion kinetic energy spectrometry method. The structure of the side chain and the position of the C-atom of the gem-diol group in the compound were established from the characteristic product ions formed from the metastable and collisionally-activated M + • and MH + ions.

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