Mass spectrometry of orellanine, a mushroom toxin, and of related bipyridine-N-oxides
β Scribed by Jean-Michel Richard; Jacques Ulrich
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 268 KB
- Volume
- 18
- Category
- Article
- ISSN
- 1076-5174
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## Abstract The electron impact mass spectra of nine solanidane __N__βoxides show, in addition to the known typical fragmentation pattern of the solanidane moiety, the fragment ions [M β C~5~H~9~]^+^ and [C~6~H~12~NO]^+^, due to thermal Cope __syn__βeliminations caused by the __N__βoxide function a