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Mass spectrometry of heterocyclic compounds—II: Electron-impact induced fragmentation of 3,5-diphenyl-1,2,4-oxadiazole

✍ Scribed by A. Selva; L. F. Zerilli; B. Cavalleri; G. G. Gallo


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
243 KB
Volume
6
Category
Article
ISSN
1076-5174

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Mass spectrometry of heterocyclic compou
✍ A. Selva; P. Traldi; P. Fantucci 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 176 KB

## Abstract Molecular orbital calculations using the semi‐empirical CNDO/2 method were carried out on the molecular ion of 3‐__p__‐NH~2~‐phenyl‐5‐phenyl‐1,2,4‐oxadiazole, whose structure had been determined by X‐ray diffraction. The calculated diatomic interaction energy values are consistent with

Electron impact induced rearrangement of
✍ Kalevi Pihlaja; Vladimir Ovcharenko; Hikmet Agirbas 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 56 KB 👁 1 views

The fragmentation behaviour of 3,4-disubstituted 1,2,4-oxadiazole-5(4H)-thiones under electron impact (EI) can be explained by postulating a predominant rearrangement to the corresponding 3,4-disubstituted 1,2,4-thiadiazole-5(4H)-ones before further fragmentation. This postulate is confirmed by a co