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Mass spectrometry of dithiophosphate metal complexes: Fragmentation of thallium(I) O,O′-diaryldithiophosphates upon electron impact

✍ Scribed by Walenty Szczepaniak; Adam S. Plaziak


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
187 KB
Volume
20
Category
Article
ISSN
1076-5174

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✍ Jan Hrušák; Martin Tkaczyk 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 478 KB

## MNDO calculations of [C3H ,0]+' predict the parallel existence of both structures of radical cations of acetone (1) and propen-2-01 (2) in electron ionization spectra. The calculated heats of formation of 1+' (A@"Do = 783.2 kJ mol-' and of 2" (AflNDo = 649.8 kJ mol-') are in very good agreement