✦ LIBER ✦

Mass spectrometry of 2-substituted adamantanes

✍ Scribed by Robert L. Greene; William A. Kleschick; George H. Wahl Jr.

Book ID: 104248402
Publisher: Elsevier Science
Year: 1971
Tongue: French
Weight: 130 KB
Volume: 12
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)97534-3

No coin nor oath required. For personal study only.

✦ Synopsis

The recent communication of Karpenko and co-workers3 prompts us to disclose our related results 4 on a much wider variety of compounds. We have found that under standard mass spectrometric conditions', the molecular ions derived from a variety of 2- substituted adamantanes (1) undergo primary loss of X * or RX depending on the relative C-X bond strength (OK X l radical stability).

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