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Mass spectrometry in structural and stereochemical problems—CXXII: Possible operation of tautomerism before and after electron-impact induced fragmentation of molecular ions

✍ Scribed by J.K. MacLeod; J.B. Thomson; Carl Djerassi


Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
493 KB
Volume
23
Category
Article
ISSN
0040-4020

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Mass spectrometry in structural and ster
✍ A. M. Duffield; Carl Djerassi; R. Neidlein; E. Heukelbach 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 346 KB

The mass spectra of five aryl (I to V) and four alkylsulfonylthioureas (VI to IX) have been recorded and mechanistic rationalizations are suggested for their principal fragmentation processes. The aryl analogs exhibited peaks in their mass spectra corresponding to skeletal rearrangements with elimin