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Mass spectrometry in structural and stereochemical problems—CLXXXV Effect of phenyl group in the mass spectra of trans-10-phenyl-2-decalone and trans-10-phenyldecalin

✍ Scribed by Robin T. Gray; Carl Djerassi

Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
764 KB
Volume
3
Category
Article
ISSN
1076-5174

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Mass spectrometry in structural and ster
Mass spectrometry in structural and stereochemical problems. CXCII. Skeletal rearrangement in the fragmentation of phenyl azide.
✍ Paul D. Woodgate; Carl Djerassi 📂 Article 📅 1970 🏛 Elsevier Science 🌐 French ⚖ 206 KB

Following the demonstrations by Meyerson and coworkers4 and Rinehart et al 5 i.-' that the M-l ion in the mass spectrum of toluene is best represented OS a tmpylium structure, analogous ring expansion pathways have been proposed to rationalize data from l3 C-labeled compounds in the quinoline, indol