Mass Spectrometry in Structural and Stereochemical Problems. CVI.1Occurrence of Alkyl and Aryl Rearrangements in the Fragmentation of Some Organic Carbonates2
β Scribed by Brown, Peter; Djerassi, Carl
- Book ID
- 115468487
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 901 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The mass spectra of five aryl (I to V) and four alkylsulfonylthioureas (VI to IX) have been recorded and mechanistic rationalizations are suggested for their principal fragmentation processes. The aryl analogs exhibited peaks in their mass spectra corresponding to skeletal rearrangements with elimin
Following the demonstrations by Meyerson and coworkers4 and Rinehart et al 5 i.-' that the M-l ion in the mass spectrum of toluene is best represented OS a tmpylium structure, analogous ring expansion pathways have been proposed to rationalize data from l3 C-labeled compounds in the quinoline, indol