Mass spectrometric behavior of trimethylsilyl derivatives of isomeric diamino-, dihydroxy- and aminohydroxynaphthalenes

✍ Scribed by J. L. Smith; J. L. Beck; W. J. A. Vandenheuvel

• Publisher: John Wiley and Sons
• Year: 1971
• Tongue: English
• Weight: 530 KB
• Volume: 5
• Category: Article
• ISSN: 1076-5174
• DOI: 10.1002/oms.1210050413

✦ Synopsis

Abstract

The mass spectrometric behavior of the di‐TMSi derivatives of diamino‐,dihydroxy‐and aminohydroxynaphthalenes is described. The presence or lack of doubly‐charged ions in the mass spectra is correlated with substituent position. Comparison is made with the spectra of the disubstituted benzenes. Other fragmentations are discussed with supporting data from TMSi‐d~9~ derivatized compounds.