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Mass spectral rearrangements in benzylidene hippuric esters

✍ Scribed by M. McCamish; J. D. White

Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
404 KB
Volume
5
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The mass spectra of a series of hippuric esters have been determined. A variety of novel rearrangements induced by the presence of a formed benzyl carbonium ion has been rationalized with the aid of high resolution measurements and isotopic and substituent labeling. An eight centered rearrangement is proposed for the observed transfer of oxygen from a nitro group to a double bond.

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