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Mass spectra of some β-keto esters. A high resolution study

✍ Scribed by Zaharie Moldovan; Nicolae Palibroda; Victor Mercea; Gheorghe Mihǎilescu; Maria Chiriac; Mircea Vlasa


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
319 KB
Volume
16
Category
Article
ISSN
1076-5174

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✦ Synopsis


Abstract

This paper presents low and high resolution mass spectra as well as fragmentation processes under electron impact for methyl, ethyl and propyl‐pivaloyl acetate. The fragmentation patterns have been established using elemental compositions of ions determined by high resolution, metastable transitions and deuterium labelling.


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The mass spectra of the C, to C, n-alkanals and a number of branched aldehydes have been obtained at a resolution sufficient to resolve the O-CH4 doublets. From the resolved spectra, a study of metastable transitions, and the spectrum of one deuterium-labelled alkanal, (n-hexanal-2,2-dz) the major f