Mass spectra of selected alkyl- and dialkyl-3-cyano-2-pyridones
β Scribed by Edwin M. Kaiser
- Book ID
- 112121800
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1968
- Tongue
- English
- Weight
- 155 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0022-152X
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## Abstract For Abstract see ChemInform Abstract in Full Text.
The mass spectra of 2-and/or 6-alkyl-3-hydroxypyridines were measured. The fragmentation processes include the loss of 1,28 and 29 u and RCN from the molecular ions. Among the characteristic ions, the [ M -11 + ions are the base peak for all of the ethyl-containing pyridines. According to a labellin
Electrospray ionization (ESI) and tandem mass spectrometry (MS/MS) experiments, as well as electronic impact (EI) and chemical ionization (CI) techniques, have been applied to the title compounds 1a-h. The observation of different fragmentation pathways in the three sets of spectra is in accord with