Mass spectra of organoboron compounds—II: The mass spectra of triphenylboroxine and its precursor phenylboronic acid
✍ Scribed by R. H. Cragg; J. F. J. Todd; A. F. Weston
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- English
- Weight
- 208 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1076-5174
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## Abstract A series of Reissert compounds containing the quinoline, isoquinoline and phthalazine nuclei show the common feature in their mass spectra of the initial loss of the N‐substituent and either of the substituents attached to the adjacent carbon atom.
The electron impact ionization and collisional activation mass spectra of a-phenylcinnamic acid and its derivatives have been studied. The loss of a phenylic hydrogen is not an important process in these molecules, unlike the unsubstituted cinnamic acids. However, in o-chloro-a-phenylcinnamic acid a